Patterned growth and cathodoluminescence of conical boron nitride nanorods

Patterned Growth of Long and Clean Boron Nitride Nanotubes on Substrates

For the first time, patterned growth of boron nitride nanotubes (BNNTs) on Si substrates has been achieved by catalytic chemical vapor deposition (CCVD). Following the boron oxide chemical pathway and our growth vapor trapping approach, high quality and quantity BNNTs can be produced. Effective catalysts have been found to facilitate the growth of BNNTs, while some critical parameters of the sy...

Observation of near- and-gap luminescence from boron nitride films

We report results from cathodoluminescence spectroscopy of boron nitride films grown on Si(100) substrates by ion-source-assisted magnetron sputtering of a hexagonal BN target. Three main peaks are observed in the near-band-gap region for hexagonal boron nitride films at energies of 4.90,5.31, and 5.50 eV We also report deep-level emission spectra of predominantly cubic boron nitride films whic...

Origin of the excitonic recombinations in hexagonal boron nitride by spatially resolved cathodoluminescence spectroscopy

Patterned Growth of Boron Nitride Nanotubes by Catalytic Chemical Vapor Deposition

For the first time, patterned growth of boron nitride nanotubes is achieved by catalytic chemical vapor deposition (CCVD) at 1200 C using MgO, Ni, or Fe as the catalysts, and an Al2O3 diffusion barrier as underlayer. The as-grown BNNTs are clean, vertically aligned, and have high crystallinity. Near band-edge absorption ∼6.0 eV is detected, without significant sub-band absorption centers. Elect...

Photon bunching in cathodoluminescence.

We have measured the second order correlation function [g^{(2)}(τ)] of the cathodoluminescence intensity resulting from the excitation by fast electrons of defect centers in wide band-gap semiconductor nanocrystals of diamond and hexagonal boron nitride. We show that the cathodoluminescence second order correlation function g^{(2)}(τ) of multiple defect centers is dominated by a large, nanoseco...